from sympy.physics.pring import wavefunction, energy from sympy.core.numbers import (I, pi) from sympy.functions.elementary.exponential import exp from sympy.functions.elementary.miscellaneous import sqrt from sympy.integrals.integrals import integrate from sympy.simplify.simplify import simplify from sympy.abc import m, x, r from sympy.physics.quantum.constants import hbar def test_wavefunction(): Psi = { 0: (1/sqrt(2 * pi)), 1: (1/sqrt(2 * pi)) * exp(I * x), 2: (1/sqrt(2 * pi)) * exp(2 * I * x), 3: (1/sqrt(2 * pi)) * exp(3 * I * x) } for n in Psi: assert simplify(wavefunction(n, x) - Psi[n]) == 0 def test_norm(n=1): # Maximum "n" which is tested: for i in range(n + 1): assert integrate( wavefunction(i, x) * wavefunction(-i, x), (x, 0, 2 * pi)) == 1 def test_orthogonality(n=1): # Maximum "n" which is tested: for i in range(n + 1): for j in range(i+1, n+1): assert integrate( wavefunction(i, x) * wavefunction(j, x), (x, 0, 2 * pi)) == 0 def test_energy(n=1): # Maximum "n" which is tested: for i in range(n+1): assert simplify( energy(i, m, r) - ((i**2 * hbar**2) / (2 * m * r**2))) == 0